Incredible Battery Breakthroughs to Watch

Developing reliable energy storage is just as,  if not more, important as improving methods of obtaining the energy itself. But among the slew  of new batteries and energy storage systems, how can you tell which tech is  worthy and which is just hype? Well, let's break down what battery  tech innovations I find personally interesting along with the scientific  grounds to back my perspectives up.

Right now I’m watching a handful of technologies  that run the gamut from making energy storage dramatically cheaper to super energy dense  batteries for the EVs, home energy storage, and consumer electronics of the future. So,  what kinds of batteries am I keeping an ion? I’m Matt Ferrell … welcome to Undecided.

This video is brought to you by  Brilliant, but more on that later. One of the bigger issues with  modern batteries is their use of critical minerals like lithium. Its  relative rarity drives up its cost, and the easiest way to extract it is by mining  and using giant lithium ponds, which isn’t conductive to protecting nearby populations or  the environment.

So what if we could swap out those rare metals and minerals for something so  common it’s probably in your kitchen right now? That’s the idea behind sodium ion batteries (or  SIBs). Salt is relatively cheap and 1,400 times more abundant in the earth’s crust than  lithium.

It's easier and less expensive to extract and purify salt for battery use, too,  so you’re looking at what could be a pretty cheap battery. And luckily, salt functions similar to  lithium, so the working principle behind a SIB should sound pretty familiar to anyone who knows  their ways around a lithium-ion battery. Anode, cathode, separator, the whole nine-yards.

The  difference is this cathode is made of sodium, so sodium atoms are shuttling  around instead of lithium. Of course, there’s a reason why we’re still  using lithium-ion batteries. Salt is notably less energy-dense than lithium, which means bigger  batteries.

So salt’s probably never going to replace lithium in the high performance  world of electric cars. But if we can find a way to boost SIBs’ performance?  Then we’d potentially have cheap, safe, and plentiful batteries that would be a great fit  for our growing stationing energy storage needs.

This has led scientists like those from  Humboldt-Universität zu Berlin (HBU) to look for ways to push their capacity even  further. And they just recently published research on an unexpected discovery  that has the potential to do just that. To increase the capacity of SIBs,  we have to increase their stability, and one promising way of doing that is through a  process called “doping.

” It’s not what it sounds like. This is a technique where the electrode  is very slightly “seasoned” with tiny fragments of another metal. It’s common practice  for lots of batteries and semiconductors, and is a good way of getting some of the  benefits of a new cathode metal without all the drawbacks or cost of building a whole  cathode out of some niche material.

In this case, the HBU scientists were looking to expand their  salt battery’s capacity by upping its stability. First, they tried scandium,  which looked great on paper, though it didn’t actually improve stability  all that much. Next, they tried magnesium, but they didn’t hold out hope for it,  because magnesium causes the exact kind of harmful redox reaction we’re trying to  avoid.

However, in a sodium-based setup, the team observed it suppressing this reaction  instead. The researchers are still studying exactly why this happens, but it's a promising  step forward for a cheap sodium battery with prospects of better longevity and stability,  great for those stationary storage applications. While we wait to see how this  new advancement affects SIBs, they’re already making commercial headway. 

CATL, China’s (and probably the world’s) leading battery manufacturer told PV magazine  that it “developed a basic industry chain for sodium ion batteries and established mass  production. ” European battery maker Northvolt unveiled their sodium NMC (Nickel Manganese  Cobalt) battery back in November, and touted it as the company's next-gen energy storage  device. And back in January, Acculon Energy unveiled plans to scale their SIB production  up to 2 GWh by mid-2024, which is right now.

There’s a lot of movement in the SIB  sector. And hopefully it won’t be too long until a residential version hits  the market, allowing homeowners with solar panels an affordable way to  store their extra energy for later. But salt isn’t the only way to store energy  … and wrapping your head around all these concepts and different chemistries can be  overwhelming.

That’s why I spent a lot of time going through the “The Chemical Reaction  ” course at today’s sponsor, Brilliant. It gets hands-on with important concepts like the state  of equilibrium, atoms and charges, and a whole lot more concepts that apply directly to batteries.  I found it extremely helpful.

Brilliant does a wonderful job breaking complex topics down with  hands-on problem solving that let you play with the concepts. It builds your critical thinking  skills through doing and not by memorizing … with thousands of interactive lessons in math, data  analysis, programming, and AI. If you’re like me, you’re probably very busy and may not think you  have the time to take a course, but Brilliant is built around bite-sized lessons that take just  a few minutes every day.

They have something for everyone, like “Scientific Thinking,” which  lets you engage with key scientific principles and theories hands on. Like comparing circuits to  understand voltage and current. To try everything Brilliant has to offer for free for a full 30  days, visit https://brilliant.

org/Undecided or click on the link in the description.  You’ll also get 20% off an annual premium subscription. Thanks to Brilliant and to  all of you for supporting the channel.

As I go down my list of “what’s hot and what’s  not” in the battery world, I would be remiss to ignore Thermal Energy Storage Device, AKA  TES devices or thermal batteries. They’re unsurprisingly, a type of device that stores  energy in the form of, you've probably guessed it, heat. And if you don’t convert the heat back into  electricity, then thermal batteries tend to have incredible round-trip efficiency (RTE).

You can  get upwards of 90% of the energy you stored back out, without losing much to time, conversion  or entropy. These are exciting because they pair really well with intermittent renewables like  wind and solar. Collect all the solar and wind energy when conditions are good, turn it to heat  and squirrel it away for later.

Simple, right? That simplicity extends to the medium that thermal  batteries use to store their heat. There’s a lot to choose from, and for the most part, they aren’t  cutting edge chemicals or space-age materials, but stuff you might find in your backyard.

For  instance, sand is looking to be one of the most promising types of thermal batteries because it  has a low specific heat — meaning it’s easy to get hot, and in a large mass, it holds onto that  heat quite well. Because it's just sand, there’s no chemical compounds with finite life spans or  breakable moving parts. Sand is cheap and easy to find compared to the chemicals and precious metals  of the other batteries that are out there.

For all those reasons and more, companies like Polar Night  are using sand batteries to heat entire districts. BatSand is going in the other direction, scaling  down its sand battery for the residential market. And while TES batteries, are dirt simple, sand  isn’t the only option.

Rondo Energy has gone with special bricks as their medium. Thermal energy  collected from renewable resources can heat the bricks up 1,500 C (2732 F), and the bricks can  store that heat for days. Better yet, Rondo claims the battery can last for over 50 years.

This  battery works in a similar fashion to Brenmiller Energy’s bGen TES, which uses crushed up rocks.  This battery achieves a lower temperature of just around 100 to 530 C (212 to 986 F), but that’s  sufficient for some manufacturing requirements and building heating. Unless, of course, you  prefer your home office kept at a toasty 500 C.

Thermal storage devices are efficient and  cheap, but their biggest downside is just how big they are. The mechanics of storing heat  means the bigger the better, so these things tend to be…cumbersome. Polar Night’s new sand battery  measures 13 by 15 meters (or about 43 by 49 feet).

Brenmiller’s bGen battery weighs 10 tons and is  12 meters long. I haven’t mentioned Vattenfall’s water-based TES in Berlin. Yes, you can make a  TES with water.

In fact, you already have one, it's your water heater. Vattenfall’s capacity is  just a bit bigger…as it’s a 45-meter (or 150 feet) tall holding 56 million liters. That’s the same  amount of water as over 22 Olympic swimming pools.

Heck, even BatSand’s tiniest residential-sized  sand battery is 40 cubic meters. And while the size of thermal batteries certainly  limits where and what we can use them for, it's not that big a deal when it comes to  the sort of application they're best suited for like stationary storage. When storing  enough energy to heat houses, buildings, or use the heat for manufacturing,  having a large footprint is a small price to pay.

Especially when  sand, rocks, and water are so cheap. When it comes to storing energy, scalability  is key, but storing energy isn’t as simple as storing more tangible objects.  If you want more energy storage, sometimes you can’t simply build a  bigger battery.

Things aren’t that easy. Enter the flow battery. These batteries have two  tanks filled with different liquids.

One tank acts as anode in the form of anolyte and the other acts  as a cathode in the form of a catholyte. Pumping them past each other, separated by a membrane,  creates an electrochemical reaction and stores energy in chemical bonds. Quite simply, the  bigger the tanks, the more energy you can store.

There’s now a ton of different flavors of  flow battery like vanadium, zinc-bromine, several organic varieties. And the one I want  to bring to your attention today is a liquid iron flow (LIF) which work like other flow  batteries, with two big tanks and separator. The twist is that both of the liquids at play  here are just a liquid electrolyte dosed with a slightly different iron(II) ion (hence the  name).

These materials are readily available, which makes these batteries cheap and easy to  produce. Having the tanks filled with different kinds of iron atoms means that, unlike other  flow batteries, if a little of tank A passes through the membrane and gets into tank B, it’s  not going to cause a permanent bit of damage. LIF batteries are nothing new, but earlier this  year the U.

S. Department of Energy’s Pacific Northwest National Laboratory (PNNL) announced  that it had made a breakthrough. Researchers added a chemical called nitrilotri-methylphosphonic  acid (or NTMPA) to their liquid electrolytes, a commercially available substance usually  used in water treatment plants to fight corrosion.

Turns out, it's also really good at  storing charged iron ions at room temperature in a neutral pH. Thanks to the NTMPA,  the research team reported that their initial design has an energy density of up to  9 watt-hours per liter (Wh/L). For reference, commercially available vanadium-flow batteries  are already much denser, at around 25 Wh/L.

That’s alright though. For a “rough draft”  on a lab bench, 9 Wh/L is a very promising start — especially for something made from easily  available materials that can scale up so well. LIFs do have some downsides to keep in mind  though.

Like thermal batteries and souffles, they just don’t travel well. That’s on top  of their relatively sluggish charge/discharge times and underwhelming energy density. But  these drawbacks aren’t really problems when it comes to applications like stationary  energy storage.

Here, scalability is key, and no battery scales up quite  as easily as the flow battery. In the past we’ve explored how other types of  flow batteries are seeing success when paired with residential solar set-ups, so who knows? One  day LIFs could be coming to a garage near you.

We've touched on Solid State Batteries (SSBs)  a few times this year, and for good reason, they’re batteries that might be able to do it  all. Having a solid core lets these batteries charge super fast, like an EV charging in  15 minutes kinda-fast. More importantly, it also fights dendrite growth, those metal  spikes that grow as you use a battery that can kill it from the inside out.

Fewer dendrites  means batteries can survive more charging cycles than even the best, current-gen king of  the battery hill. At least in theory… So, if SSBs aren’t yet living up to their  intention just yet, why do I think they’re worth watching in 2024? They were one of those  technologies that was always just another 5 or 10 years away from being reality because of how  difficult they are to manufacture, let alone mass produce.

Both QuantumScape and Solid Power have  tackled manufacturing issues in their own ways. QuantumScape has developed advanced processors  that help deal with the notoriously tricky task of making the solid state separators for  their anode-free battery design. And they claim they'll soon be able to mass produce  their batteries at gigawatt scale.

Meanwhile, the core of Solid Power’s SSB is made from  sulfides. These are less temperamental than traditional solid state materials, which  should make it fairly easy for Solid Power to manufacture them with commonplace  roll-to-roll technology. Solid Power is building their factories right now, planning  to make enough SSBs for 800,000 EVs by 2028.

So while these SSBs aren’t surpassing  traditional lithium just yet, they are super promising. Once solid  state batteries are on the market, they could mature fast. That could see us  work out the kinks and drop the costs so these batteries can finally live up to their  super-dense promise.

But only time will tell. Let’s close out with silicon batteries, the most  powerful ones on this list. These are already seeing some commercial success and companies  like Amprius, OneD and Sila Nanotechnologies are hoping to push it even further.

Silicon  is amazing at storing lithium ions. It takes just one silicon atom to store four lithium  ions. That makes silicon anodes up to 24 times more efficient than graphite anodes of your  typical lithium-ion battery.

Being insanely energy-dense and relatively lightweight  makes silicon batteries a theoretical great fit for the next generation of phones,  wearables, and maybe even electric vehicles. The big drawback is that silicon likes lithium a  little too much. Reacting with the lithium ions can make the silicon anode dramatically balloon  up and break the battery.

Amprius and OneD are tackling this issue by growing nanowires. These  make excellent pathways for lithium ions to zoom across, making for an energy dense battery.  The space between the wires gives the swelling silicon some wiggle room.

Nanotech has also led  to Sila’s solution: micrometer-size particles of nanostructured silicon and other materials that  are protected by a porous scaffold. It’s another way of giving those ions freeways to cruise while  making sure the silicon doesn’t swell out of control. From the outside, it looks and feels like  a commonplace battery anode, which should allow them to use pre-existing battery manufacturing  gear to mass produce their silicon batteries.

Of course, making nanotech at scale is very  challenging, but these companies are pushing ahead and getting close to commercialization.  Amprius has a working factory in Colorado, its product is on the market, and earlier this  year, the company completed qualification for its SiMaxx mass production tool. Amprius  claims this will help its team increase production to 2 MWh of silicon batteries  in 2025, which is 10 times what they expect to produce this year.

Sila has two factories,  one in California and one in Washington state, with a combined (expected)  capacity of about 150 GWh. Any one of these companies could open the door to silicon batteries. And that could mean a  revolution for just about every piece of tech that wants more power in a smaller  package… which is basically everything.

That’s all just a taste of what’s to come.  We’d be here forever if I were to list all the exciting new battery tech to watch in  2024 and beyond. It feels the battery sector is on the cusp of a transformative phase, one  where lithium will still have its applications, but we’ll have a lot of other viable alternatives.

Whether it's stationary storage, EVs or anything  else, I can’t wait to see what niches these batteries find and how they’ll make things more  green, more efficient, and just plain better. But what do you think? What batteries  are you keeping an eye on?

Jump into the comments and let me know and  be sure to listen to my follow up podcast Still TBD where we’ll keep  this conversation going. Thanks as always to my patrons for your continued  support. I’ll see you in the next one.